二氧化硅基相变材料综述

Abstract: Efficient thermal energy harvesting using phase change materials (PCMs) has great potential for thermal energy storage and thermal management applications. Benefiting from these merits of pore structure diversity, convenient controllability, and excellent thermophysical stability, SiO2-based composite PCMs have comparatively shown more promising prospect. In this regard, the microstructure-thermal property correlation of SiO2-based composite PCMs is still unclear despite the significant achievements in structural design. To enrich the fundamental understanding on the correlations between the microstructure and the thermal properties, we systematically summarize the state-of-the-art advances in SiO2-based composite PCMs for tuning thermal energy storage from the perspective of tailoring chemistry strategies. In this review, the tailoring chemistry influences of surface functional groups, pore sizes, dopants, single shell, and hybrid shells on the thermal properties of SiO2-based composite PCMs are systematically summarized and discussed. This review aims to provide in-depth insights into the correlation between structural designs and thermal properties, thus showing better guides on the tailor-made construction of high performance SiO2-based composite PCMs. Finally, the current challenges and future recommendations for the tailoring chemistry are also highlighted.

Figure 1. Tailoring Chemistry Strategies of Silica-Based Composite PCMs for Thermal Energy Storage

文献链接：Xiao Chen1*, Zhaodi Tang1, Yueqi Chang, Hongyi Gao, Piao Cheng, Zhang Tao, Junjun Lv. Toward tailoring chemistry of silica-based phase change materials for thermal energy storage. iScience, 2020, 23, 101606.