碳量子点衍生的高石墨化碳基相变储热材料

Abstract: One major barrier obstructing their scale engineered adoption of phase change materials (PCMs), currently, is their low thermal conductivity, which drastically constrains the power capacity. Our target is to enhance the PCMs thermal conductivity without evidently altering other thermal property criteria. Herein, we propose a facile, low-cost and controllable strategy to construct compactly interconnected 3D celosia-like highly graphitized thermally conductive network carbon via carbon quantum dots (CQDs) deriving from acetone and divinyl benzene (DVB). Novel function of CQDs is firstly developed for superior thermal energy harvesting, thus expanding their conventional fluorescence and catalysis field to novel thermal energy storage. Importantly, our constructed 3D graphitized network carbon better infiltrates macromolecule polyethylene glycol (PEG) and fully releases crystallization via controllable crosslinking reaction. This strategy simultaneously integrates sufficient power capacity and incremental thermal conductivity (enhanced by 236%) of the PCMs, and thermal enthalpy is considerably approaching the theoretical value. Alternatively, the composite PCMs are thermally and durably stable. These results indicate that resulting shape-stabilized PCMs are a very promising candidate for renewable thermal energy storage in virtue of the superior comprehensive properties.

Figure 1. (a) Schematic illustration of PEG8000@ CQDs-derived 3D porous carbon composite PCMs, (b) TEM images and particle diameter distribution, (c, d) XPS spectrum.

Figure 2. DSC thermogram of PEG8000@ CQDs-derived porous carbon composite PCMs.

文献链接：Xiao Chen, Hongyi Gao, Mu Yang⁎, Wenjun Dong, Xiubing Huang, Ang Li, Cheng Dong, Ge Wang⁎. Highly graphitized 3D network carbon for shape-stabilized composite PCMs with superior thermal energy harvesting. Nano Energy, 2018, 49, 86–94.